Presence Of Pesticides In Water Research Articles

Prevalence and concentration of pesticides in European waters: A protocol for systematic review and meta-analysis.

There is currently a growing interest in the so-called emerging pollutants, such as pesticides, pharmaceuticals, personal hygiene care products, drugs, etc., whose presence in natural ecosystems is not necessarily recent, but the development in latest years of new and more sensitive methods of analysis has allowed their detection. They can be present in the natural environment, food, and many products of everyday origin, which suggests that human exposure to them is massive and universal. Therefore, the study of this type of substances is becoming one of the priority lines of research of the main agencies dedicated to the protection of public and environmental health, such as the World Health Organization (WHO), United States Environmental Protection Agency (USEPA) or European Union (EU). In this sense, it is of vital importance to know the nature and quantity of this type of contaminants, to establish preventive mechanisms that minimize its presence in aquatic systems, with special requirements for human consumption. This study aimed to describe a protocol for a systematic review and meta-analysis to assess the status of pesticides in European waters. We will search for original studies in the PubMed/Medline, Scopus, Web of Science, EMBASE, ScienceDirect databases. Prevalence studies of emerging contaminants (pesticides) in water resources (watersheds, aquifers, rivers, marine and springs), wastewaters (influent and effluent), and drinking water should be included. Two reviewers will independently screen and assess the included studies, with any disagreements being resolved by a third reviewer. We will summarize the findings using a narrative approach and, if possible, conduct a quantitative synthesis (meta-analysis). We will conduct the protocol following the Preferred Reporting Items for Systematic Review and Meta-Analyses Protocols (PRISMA-P) guidelines. The review will summarize the current evidence on the presence of pesticides in European waters such as glyphosate, chlorpyrifos, pyrethroid pesticides, neonicotinoid pesticides, and/or fungicides, in samples of different water resources like wastewaters and drinking water. We expect that this systematic review will establish preventive mechanisms that minimize the presence of pesticides in water in the environment.

Exposure to common pesticides utilized in northern rice fields of Iran affects survival of non-target species, Pelophylax ridibundus (Amphibia: Ranidae).

Amphibians are the most important vulnerable non-target vertebrate group that are affected by pesticides. Most previous studies have confirmed the destructive effects of pesticides. But, so far, no comprehensive studies have been carried out in Iran. Therefore, to estimate the mortality rate of frogs during the growing season in different cultivating systems, we examined the presence of pesticides in water and substrate as indicators of habitat quality and in the liver tissue of Marsh frog Pelophylax ridibundus (Pallas, 1771), enclosed in the prepared cages at five rice paddy fields in Mazandaran province, Iran. The measurement of pollution was done using mass gas chromatography method and statistical analyses by Minitab software. Furthermore, the probable movement pattern of free frogs was analyzed using capture-mark-recapture method. Thirteen pesticides were detected both in the habitat and in frogs' liver tissue. Among them ß-Mevinphos, Fenitrothion, Bromofos, and Trifluralin had the most frequent occurrence in liver tissue, and Diazinon with concentrations up to 517.8μg/Kg had the highest concentration. Furthermore, there is a significant correlation (R2 > 0.96) between water quality and frogs' contamination, whereas, no correlation was observed between substrate pollution and frogs' contamination. Pesticide concentrations were higher in two stations but lower than lethal doses to frogs, so that no mortality was observed at any of the stations. However, some specimens had a considerable muscle atrophy. Despite no significant movement pattern was detected, we can expect that if this trend continues, in a long term, they will face a reduction in the survival rate.

Ecological impacts of pesticides on Astyanax jacuhiensis (Characiformes: Characidae) from the Uruguay river, Brazil

Brazilian freshwater ecosystems are continuously exposed to pesticides and domestic sewage. The Uruguay River was chosen for this study because of its international importance, as it flows through Brazil, Argentina, and Uruguay. It receives contaminants such as pesticides and domestic residues. Thus, the aim of this study to assess the accumulation of pesticides in muscle of the fish Astyanax jacuhiensis, its biochemical responses, and the presence of pesticides in water. In total, seven pesticides were registered in water from both river sites. Eight pesticides were detected in fish muscle. The biochemical responses showed that brain lipid peroxidation (LPO) and protein carbonyl (PC) in A. jacuhiensis were higher in the summer. Muscle showed the highest LPO levels in the spring and the highest PC in the summer. Liver LPO and PC levels were higher in the spring and summer. In the gills, the PC was higher in the spring and the LPO in the spring and winter. In the brain and in the gills, glutathione-S-transferase activity was high in the summer and autumn. Catalase activity was lower during the winter and spring. Non-protein thiol (NPSH) levels were lower in the brain in the winter and spring. Muscle tissue showed lower NPSH in the winter (site 1). Liver NPSH showed increased levels in liver in the spring and winter (site 2). The biochemical results clearly is related to pesticides and/or to the presence of other contaminants in the water such as metals or domestic sewage. The accumulation of pesticides in fish muscle added evidence that pesticides have been used in the area surrounding the Uruguay River. In conclusion, the biomarkers assayed in the present study could be used in future investigations considering other sampling sites along Uruguay River.

Assessment of Health Risk due to Pesticide Residues in Fruits, Vegetables, Soil, and Water

The present study was conducted to assess the contamination and health risk due to the presence of pesticides in fruits and vegetables. A total of six vegetable samples, 3 fruit samples, 7 soil samples, and 6 water samples were collected from three different sampling points. High-performance liquid chromatography using acetonitrile and water solvent system was employed for the quantitative and qualitative analysis. The pesticides having the highest health risk in vegetables were Bifenthrin and Difenoconazole as their health risk index was found to be exceeding the cut off value of 1. Imidacloprid was found in all vegetable samples but had no associated health risk, as all the health risk indices for imidacloprid were below the cut off value of 1. The pesticide Glyphosate detected in only one sample had no health risk associated with it. Health risks in fruits were the highest for Amamectin, Bifenthrin, and Difenoconazole and were crossing the threshold limit of 1. The results reveal the health risk indices of Bifenthrin and Difenoconazole range from 7.8 to 12.46 in vegetables and from 2.704 to 30.454 in fruits, hence, posing a serious threat to human health. Amamectin, although detected in only fruit and water samples, had the highest health risk of 30.454. Imidacloprid and Glyphosate found in every fruit sample had no associated health risk. The results revealed the presence of pesticides in water, soil, fruit, and vegetable samples. Consumers utilizing these vegetables and fruits are under potential health risks due to the presence of pesticides in soil and water. Practical Applications. In this study, an analytical method for detecting pesticides in a variety of environmental matrices including fruits, vegetables, water, and the soil is presented and the health risk associated with the presence of pesticides in a wide range of fruits and vegetables is assessed. It is highly significant because in developing countries agricultural activities contribute majorly toward the total gross domestic product and pesticides are extensively used to control, prevent, devastate, and diminish any harmful pest that destroys crops.

A multidisciplinary perspective to protect the quality of water in natural wetlands. A case study in Oaxaca, Mexico

Abstract In Mexico, 142 sites covering almost nine million hectares are listed as Ramsar wetlands. Given the complaints of local inhabitants regarding water quality, and the interest of the federal government for setting up a plan for wetlands protection, we evaluated the ecological condition of a wetland in rural Oaxaca, Mexico. Existing water quality data were compiled and analyzed. Among the parameters of interest were temperature, pH, DO, N, P, and fecal contamination. Even though microbial contamination was a primary concern, a more important worry to local users was the presence of pesticides in water due to inadequate disposal of empty containers and runoff from upstream farmlands. Public meetings with water users, researchers, and local and federal personnel were held to get the opinion about strategies for protection of the wetlands. Outcomes of the decision meetings using a decision-support system highlighted that to preserve the wetlands, the implementation of riparian vegetation (buffer zone) and the management of surface water should be considered as conservation practices. Law enforcement would improve the watershed and wetlands' health for preventing further deterioration. Because of the success in getting public participation and input, the approach will likely be replicated in other parts of the country.

Monitoring and environmental risk assessment of pesticide residues and some of their degradation products in natural waters of the Spanish vineyard region included in the Denomination of Origin Jumilla

Water pollution by pesticides used in agriculture is currently a major concern both in Spain and in Europe as a whole, prompting the need to evaluate water quality and ecological risk in areas of intensive agriculture. This study involved monitoring pesticide residues and certain degradation products in surface and ground waters of the Denomination of Origin (DO) Jumilla vineyard area in Spain. Sixty-nine pesticides were selected and evaluated at twenty-one sampling points using a multi-residue analytical method, based on solid-phase extraction (SPE) and analysis by liquid chromatography coupled with mass spectrometry (LC-MS), providing reliable results. Twenty-six compounds from those selected were detected in the samples analyzed (eleven insecticides including one degradation product, nine herbicides, and six fungicides) and fifteen of them were found in concentrations over 0.1 μg L−1 (upper threshold established by the EU for pesticides detected in waters for human consumption). Indoxacarb was present in more than 70% of the samples, being the most frequently detected compound in water samples. Some pesticides were ubiquitous in all the water samples. Ecotoxicological risk indicators, toxic units (TUs) and risk quotients (RQs), for algae, Daphnia magna and fish were calculated to estimate the environmental risk of the presence of pesticides in waters. The compounds with the highest risk were the herbicides pendimethalin, with RQ values > 1 for the three aquatic organisms, and diflufenican, posing a high risk for algae and fish, and the insecticide chlorpyrifos, with a high risk for Daphnia magna and fish. The ∑TUi determined for water at each sampling point posed only a high risk for the three aquatic organisms in a sample. These results are important for considering the selection of pesticides with less environmental risk in intensive agricultural areas.

Optimized terbium doped Ti/PbO2 dimensional stable anode as a strong tool for electrocatalytic degradation of imidacloprid waste water.

The presence of pesticides in water has emerged as a momentous environmental issue over the past decades. Herein, a terbium doped Ti/PbO2 (denoted as Ti/PbO2-Tb) dimensionally stable Ti/PbO2-Tb anode has been successfully prepared by one-step electrodeposition path for electrocatalytic degradation of imidacloprid (IMD) wastewater with high efficiency. Ti/PbO2-Tb electrode presents higher oxygen evolution potential, lower charge transfer resistance, stronger stability, longer service lifetime and outstanding electrocatalytic activity than Ti/PbO2 electrode. The optimum condition for IMD oxidation is obtained by analyzing the effects of some critical operating parameters including temperature, initial pH, current density and electrolyte concentration. It is proved that 70.05% of chemical oxygen demand and 76.07% of IMD are removed after 2.5 h of degradation under current density of 8 mA cm-2, pH 9, temperature 30 °C and 7.0 g L-1 NaCl electrolyte. In addition, the electrode displays commendable energy saving property as well as favorable reusability. The degradation mechanism of IMD is proposed by analyzing the intermediates identified by LC-MS. The present research provides a feasible strategy to degrade IMD wastewater by Ti/PbO2-Tb electrode.

Impact of Spent Mushroom Substrates on the Fate of Pesticides in Soil, and Their Use for Preventing and/or Controlling Soil and Water Contamination: A Review.

Intensive crop production involves a high consumption of pesticides. This is a cause of major environmental concern because the presence of pesticides in water is becoming increasingly common. Physicochemical methods based on soil modification with organic residues have been developed to enhance the immobilization and/or degradation of pesticides in agricultural soils, which may control both the diffuse and the point pollution of soils and waters. This review summarizes the influence of spent mushroom substrate (SMS) on the environmental fate of pesticides when both are simultaneously applied in agriculture. The processes of adsorption, leaching and dissipation of these compounds in SMS-amended soils were evaluated at laboratory and field scale. Relationships were established between the experimental parameters obtained and the properties of the soils, the SMS, and the pesticides in order to determine the effect that the application of SMS in agricultural soils has on the environmental impact of pesticides. Accordingly, this review highlights the use of SMS as a strategy for the prevention and/or control of soil and water contamination by pesticides to strike a balance between agricultural development and the use of these compounds.

Patterns of presence and concentration of pesticides in fish and waters of the Júcar River (Eastern Spain)

The Júcar River, in a typical Mediterranean Basin, is expected to suffer a decline in water quality and quantity as a consequence of the climate change. This study is focused on the presence and distribution of pesticides in water and fish, using the first extensive optimization and application of the QuEChERS method to determine pesticides in freshwater fish. Majority pesticides in water – in terms of presence and concentration – were dichlofenthion, chlorfenvinphos, imazalil, pyriproxyfen and prochloraz (associated with a frequent use in farming activities), as well as buprofezin, chlorpyriphos and hexythiazox. In fish, the main compounds were azinphos-ethyl, chlorpyriphos, diazinon, dimethoate and ethion. The analysis of bio-concentration in fish indicated differences by species. The maximum average concentration was detected in European eel (a critically endangered fish species). The wide presence of pesticides in water and fish suggests potential severe effects on fish populations and other biota in future scenarios of climate change, in a river basin with several endemic and endangered fish species. The potential effects of pesticides in combination with multiple stressors require further research to prioritize the management of specific chemicals and suggest effective restoration actions at the basin scale.

Approaches for regulating water in South Africa for the presence of pesticides

The public health significance of pesticide pollution of water sources in South Africa has received little attention from policy-makers and regulators, unlike microbiological quality of potable water. This anomaly is reflected in the current legislation in South Africa which is marked by inadequate regulatory standards for pesticides in water. Due to high costs, technical constraints and shortage of laboratory skills for pesticide analyses in South Africa, the poor regulatory framework has no monitoring data on which to base policy. In contrast, international experience in setting standards for maximum permissible levels of pesticides in water is extensive. The different approaches used by the World Health Organisation, the United States Environmental Protection Agency and the European Union are outlined, as well as the assumptions underlying these different approaches. Drawing on these models, recommendations are made as to how to integrate concerns for pesticide safety in environmental regulation and risk assessment in South Africa. Such measures would ensure consistency with recent developments in environmental management in South Africa that give primacy to a number of key environmental policy principles. A public health perspective should ensure that growing international concerns for long-term adverse health and environmental impacts arising from the presence of pesticides in water are adequately addressed in regulatory controls in South Africa.

Pesticides detection in water and humic solutions using porous silicon technology

A simple and low-cost optical sensor, based on porous silicon nanotechnology, has been used to detect and quantify the presence of pesticides in water and humic acid solutions. A well defined optical signal variation is registered even at low concentration as 1 ppm. The phenomenon can be ascribed to the capillary infiltration of liquid into the pores, which makes possible to detect changes in the refractive index of the liquid solution up to 0.0002.

Enzyme immunoaffinity chromatography--a rapid semi-quantitative immunoassay technique for screening the presence of isoproturon in water samples.

Immunochromatography devices based on the principles of affinity chromatography and enzyme immunoassay have been developed to illustrate the possibility of providing extra-laboratory 'in the field' tests for pesticide monitoring. Isoproturon was chosen in this study as an example though other pesticides could have been used provided a suitable antiserum existed. The test system was prepared by immobilising isoproturon antibodies to porous silica which were then packed into disposable columns (immunoaffinity columns). The addition of chromagen-substrate 3,3',5,5'-tetramethylbenzidine into the immunoaffinity columns, after the application of a mixture containing an equal volume of isoproturon samples or isoproturon standard solutions with a fixed concentration of isoproturon labelled with horseradish peroxidase, allowed the development of a colorimetric portable assay capable of screening samples qualitatively for the presence of isoproturon in water. Samples with contamination levels of 0.12 microgram l-1 isoproturon and above were visually identified as positive samples in comparison to the zero standard sample. However, samples with concentrations below this level would be considered as negative (no isoproturon present at this limit of detection). The duration of the sample screening procedure on the column was less than 25 min making the technique highly suitable for a rapid estimate of isoproturon concentrations. Furthermore, the system could estimate isoproturon concentrations in water from various sources with no requirement for sample preparation. Therefore, the technique is ideally suited for monitoring the presence of pesticides in water. Further refinement of the assay could result in a test suitable for use by non-skilled personnel in extra-laboratory locations (e.g., a mobile or field laboratory).

Recent epidemics of poisoning by pesticides

The mechanisms of production of collective poisoning by pesticides have been: contamination of foods consumed by man, cutaneous contact and occupational exposure. It is possible to distinguish 4 groups of alimentary epidemics: (1) contamination during transport or storage; (2) ingestion of seed dressed for sowing; (3) use of pesticides in food preparation because of their organoleptic similarity to alimentary products; (4) presence of pesticides in water or food owing to unsafe use of pesticides. Occupational exposure affects clusters of workers in pesticide manufacture, pesticide application and crop management. Some episodes of every kind of the mentioned groups have been published recently.